Two-Dimensional Nematic Colloidal Crystals Self-Assembled by Topological Defects
When colloidal particles are confined to a few micrometer-thick layer of a nematic liquid crystal form two-dimensional crystal structures that are bound by topological defects. Two basic crystalline structures were observed, depending on the ordering of the liquid crystal around the particle. Colloidal particles inducing quadrupolar order crystallize into weakly bound two-dimensional ordered structure, where the particle interaction is mediated by the sharing of localized topological defects. Colloids inducing dipolar order are strongly bound into antiferroelectric-like two-dimensional crystallites of dipolar colloidal chains.
MUŠEVIČ, Igor, ŠKARABOT, Miha, TKALEC, Uroš, RAVNIK, Miha, ŽUMER, Slobodan. Two-dimensional nematic colloidal crystals self-assembled by topological defects. Science 313, 954-958 (2006).